DMCA
Statistics for Experimenters (2005)
| Citations: | 674 - 1 self |
BibTeX
@MISC{Hunter05statisticsfor,
author = {Gerald O. Hunter and Matthias Zeller and Brian D. Leskiw and Bruker Smart and Apex Ccd},
title = {Statistics for Experimenters},
year = {2005}
}
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Abstract
R factor = 0.052; wR factor = 0.114; data-to-parameter ratio = 18.4. The title compound, [Zn(C8H10F3O2)2(CH4O)2], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethylhexane-2,4dionate. The bis--diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octahedral with basically no distortion, and the methanol molecules are in trans positions with respect to one another. The planes of the-diketonate and the ZnO4 unit are tilted by 18.64 (10) against each other. O—H O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100]. Related literature For information regarding the synthesis of various metal-diketonates refer to Watson & Lin (1966). For mass spectrometry related articles see Lerach & Leskiw (2008) and Schildcrout (1976). For a variety of applications and properties of metal-diketonate complexes refer to Burtoloso (2005), Katok et al. (2006) and Condorelli et al. (2007). Lerach et al. (2007) report the structure of the Co analogue of the title compound.
Keyphrases
title compound co analogue zno4 unit methanol hydroxyl group data-to-parameter ratio watson lin trans position hydrogen bond crystallographic inversion center metal-diketonate complex related literature zinc complex lerach leskiw diketonate atom wr factor various metal-diketonates bi diketonate complex mass spectrometry related article methanol molecule
