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Thermal Contact I. Symmetries ruled by Exchange Entropy Variations, (2013)

by F Cornu, M Bauer
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Thermal Contact. II. A Solvable Toy Model

by F. Cornu, M. Bauer , 2013
"... A toy model for thermal contact consists of a two-spin system, where each spin is flipped by a thermostat. The transition rates are determined from the modified detailed balance discussed in Ref.[1]. Generalized heat capacities, excess heats, the housekeeping entropy flow and the thermal conductivit ..."
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A toy model for thermal contact consists of a two-spin system, where each spin is flipped by a thermostat. The transition rates are determined from the modified detailed balance discussed in Ref.[1]. Generalized heat capacities, excess heats, the housekeeping entropy flow and the thermal conductivity are calculated. The joint probability distribution of the heat cumulated exchanges at any time is computed explicitly. We obtain the large deviation func-tion of heat transfer via a variety of approaches. In particular, by a saddle-point method performed accurately, we obtain the explicit expressions not only of the large deviation func-tion, but also of the amplitude prefactor, in the long-time probability density for the heat current. The following physical properties are discussed: the effects of typical time scales of the mesoscopic dynamics which do not appear in equilibrium statistical averages and the limit of purely energy dissipation towards a thermostat when its temperature goes to zero. We also derive some properties of the fluctuations in the two-spin system viewed as a thermal machine performing thermodynamical cycles. PACS: 05.70.Ln, 02.50.Ga, 05.60.Cd
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...ract A toy model for thermal contact consists of a two-spin system, where each spin is flipped by a thermostat. The transition rates are determined from the modified detailed balance discussed in Ref.=-=[1]-=-. Generalized heat capacities, excess heats, the housekeeping entropy flow and the thermal conductivity are calculated. The joint probability distribution of the heat cumulated exchanges at any time i...

This content has been downloaded from IOPscience. Please scroll down to see the full text. Thermal contact through a diathermal wall: a solvable toy model Thermal contact through a diathermal wall: a solvable toy model Thermal contact through a diathermal

by F Cornu , M Bauer
"... Abstract. A diathermal wall between two heat baths at different temperatures can be mimicked by a layer of independent spin pairs with some internal energy and where each spin σ a is flipped by thermostat a (a = 1, 2). The transition rates are determined from the modified detailed balance. Generali ..."
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Abstract. A diathermal wall between two heat baths at different temperatures can be mimicked by a layer of independent spin pairs with some internal energy and where each spin σ a is flipped by thermostat a (a = 1, 2). The transition rates are determined from the modified detailed balance. Generalized heat capacities, excess heats, the housekeeping entropy flow and the thermal conductivity in the steady state are calculated. The joint probability distribution of the heat cumulated exchanges at any time is computed explicitly. We obtain the large deviation function of heat transfer via a variety of approaches. In particular, by a saddle-point method performed accurately, we obtain the explicit expressions not only of the large deviation function, but also of the amplitude prefactor, in the long-time probability density for the heat current. The following physical properties are discussed: the effects of typical time scales of the mesoscopic dynamics which do not appear in equilibrium statistical averages and the limit of strict energy dissipation towards a thermostat when its temperature goes to zero.
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... with transition rates bound to obey the modified detailed balance (2.3). This is the case for the long-time fluctuation relation (1.1) and for the following finite-time detailed fluctuation relation, valid for a protocol where a piece of material with non-negligible internal energy, initially at inverse temperature β0, is put as a diathermal interface between two thermal baths at inverse temperatures β1 and β2 at time t = 0: the joint probability for measuring the heat amounts Q1 and Q2 during a finite time t satisfies the relation P (Q1,Q2; t)/P (−Q1,−Q2; t) = exp[(β0 − β1)Q1 + (β0 − β2)Q2] [16]. In the present paper, within the latter class of models, we consider a very simple one: • The interface consists of two layers. • Each layer consists in a number of independent identical microscopic systems, which we call spins, because we assume that they have only two states. Without loss of generality these states can be labeled ±1, so that we are dealing with (classical Ising) spins. Of course, in a more realistic thermal contact, some interactions between spins in the same layer, reflecting the (two-dimensional) geometry of the interface, would be present. But there is no obvious reason...

Affinity and Fluctuations in a Mesoscopic Noria

by M. Bauer, F. Cornu, Bauer Michel , 2014
"... We exhibit the invariance of cycle affinities in finite state Markov processes under various natural probabilistic constructions, for instance under conditioning and under a new combina-torial construction that we call “drag and drop”. We show that cycle affinities have a natural probabilistic meani ..."
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We exhibit the invariance of cycle affinities in finite state Markov processes under various natural probabilistic constructions, for instance under conditioning and under a new combina-torial construction that we call “drag and drop”. We show that cycle affinities have a natural probabilistic meaning related to first passage non-equilibrium fluctuation relations that we establish.
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...w is a probability (i.e.∑ C w(C) = 1), leading to detailed balance. – Finally, we emphasize that anti-symmetry is related to an interpretation of exchanges with reservoirs, and simple physical models =-=[2, 8, 9]-=- support the interpretation that (C′|S|C) is just the variation of entropy of the reservoirs when the system transits from C to C′. Our next aim is to recall a standard entropy argument, which is esse...

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