The cross-coupling of the optically active silane (3(2-cyclohexenyl)difluorophenylsilane (1) with aryl halide or date, catalysed by Pd(PPh,),, in the presence of fluoride ion proceeds stereospecifically, strongly depending upon the nature of the reactants (1996)

by M SHIMIZU HIRABAYASHI, A MOM, Organometallics