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28
Fourier’s law for a harmonic crystal with self-consistent stochastic reservoirs
, 2004
"... We consider a d-dimensional harmonic crystal in contact with a stochastic Langevin type heat bath at each site. The temperatures of the ‘‘exterior’ ’ left and right heat baths are at specified values TL and TR, respectively, while the temperatures of the ‘‘interior’ ’ baths are chosen self-consisten ..."
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Cited by 7 (0 self)
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We consider a d-dimensional harmonic crystal in contact with a stochastic Langevin type heat bath at each site. The temperatures of the ‘‘exterior’ ’ left and right heat baths are at specified values TL and TR, respectively, while the temperatures of the ‘‘interior’ ’ baths are chosen self-consistently so that there is no average flux of energy between them and the system in the steady state. We prove that this requirement uniquely fixes the temperatures and the self consistent system has a unique steady state. For the infinite system this state is one of local thermal equilibrium. The corresponding heat current satisfies Fourier’s law with a finite positive thermal conductivity which can also be computed using the Green–Kubo formula. For the harmonic chain (d=1) the conductivity agrees with the expression obtained by Bolsterli, Rich, and Visscher in 1970 who first studied this model. In the other limit, d ± 1, the stationary infinite volume heat conductivity behaves as (add) −1 where ad is the coupling to the intermediate reservoirs. We also analyze the effect of having a non-uniform distribution of the heat bath couplings. These results are proven rigorously by controlling the behavior of the correlations in the thermodynamic limit. KEY WORDS: Fourier’s law; harmonic crystal; non-equilibrium systems; thermodynamic limit; Green–Kubo formula.
A local fluctuation theorem
- Journal of Physics A
, 1998
"... a simple consequence of a time reversal symmetry; it deals with motions which are chaotic in the strong mathematical sense of being hyperbolic and transitive (ie are generated by smooth hyperbolic evolutions on a smooth compact surface (the “phase space”) and with a dense trajectory, also called Ano ..."
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Cited by 6 (2 self)
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a simple consequence of a time reversal symmetry; it deals with motions which are chaotic in the strong mathematical sense of being hyperbolic and transitive (ie are generated by smooth hyperbolic evolutions on a smooth compact surface (the “phase space”) and with a dense trajectory, also called Anosov systems) and “furthermore are time reversible”. In such systems any initial data, with the exception of a set of zero volume in phase space, have the same statistical properties in the sense that all smooth observables admit a time average independent of the initial data and expressed as an integral with respect to a probability distribution on phase space, called the ”natural stationary state”, or simply the “stationary state”. The theorem provides, asymptotically in the observation time, a quantitative and parameter free relation between the stationary state probability of observing a value of the average entropy production rate and its opposite. Although there are quite a few examples of mechanical systems which are hyperbolic and transitive in the above mathematical sense, the fluctuation theorem acquires
Properties of stationary nonequilibrium states in the thermostatted periodic Lorentz gas III: The many colliding particles system, in preparation
"... We study numerically and analytically the properties of the stationary state of a particle moving under the influence of an electric field E in a two dimensional periodic Lorentz gas with the energy kept constant by a Gaussian thermostat. Numerically the current appears to be a continuous function o ..."
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Cited by 5 (0 self)
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We study numerically and analytically the properties of the stationary state of a particle moving under the influence of an electric field E in a two dimensional periodic Lorentz gas with the energy kept constant by a Gaussian thermostat. Numerically the current appears to be a continuous function of E whose derivative varies very irregularly, possibly in a discontinuous manner. We argue for the non differentiability of the current as a function of E utilizing a symbolic description of the dynamics based on the discontinuities of the collision map. The decay of correlations and the behavior of the diffusion constant are also investigated. KEY WORDS: Thermostatted Lorentz gas; steady state current; smoothness; regularity; symbolic dynamics.
Heat and Fluctuations from Order to Chaos
, 2008
"... The Heat theorem reveals the second law of equilibrium Thermodynamics (i.e.existence of Entropy) as a manifestation of a general property of Hamiltonian Mechanics and of the Ergodic Hypothesis, valid for 1 as well as 10 23 degrees of freedom systems, i.e. for simple as well as very complex systems, ..."
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Cited by 5 (5 self)
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The Heat theorem reveals the second law of equilibrium Thermodynamics (i.e.existence of Entropy) as a manifestation of a general property of Hamiltonian Mechanics and of the Ergodic Hypothesis, valid for 1 as well as 10 23 degrees of freedom systems, i.e. for simple as well as very complex systems, and reflecting the Hamiltonian nature of the microscopic motion. In Nonequilibrium Thermodynamics theorems of comparable generality do not seem to be available. Yet it is possible to find general, model independent, properties valid even for simple chaotic systems (i.e. the hyperbolic ones), which acquire special interest for large systems: the Chaotic Hypothesis leads to the Fluctuation Theorem which provides general properties of certain very large fluctuations and reflects the time-reversal symmetry. Implications on Fluids and Quantum systems are briefly hinted. The physical meaning of the Chaotic Hypothesis, of SRB distributions and of the Fluctuation Theorem
Positivity of Entropy Production
, 2000
"... We discuss the positivity of the mean entropy production for stochastic systems driven from equilibrium, as it was defined in [7, 8]. Non-zero entropy production is closely linked with violation of the detailed balance condition. This connection is rigorously obtained for spinflip dynamics. We remar ..."
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Cited by 4 (3 self)
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We discuss the positivity of the mean entropy production for stochastic systems driven from equilibrium, as it was defined in [7, 8]. Non-zero entropy production is closely linked with violation of the detailed balance condition. This connection is rigorously obtained for spinflip dynamics. We remark that the positivity of entropy production depends on the choice of time-reversal transformation, hence on the choice of the dynamical variables in the system of interest. Keywords: entropy production, nonequilibrium Gibbs states. 1 Motivation Boltzmann's famous formula S = log W relates the Clausius thermodynamic entropy S with the configurational entropy log W ; W denotes the `thermodynamic probability' obtained by `counting the number of microstates compatible with the values of a given set of macro-variables' for a system containing a huge amount of degrees of freedom (we ignored additive and multiplicative constants). This relation marks a triumph in connecting, via statistical consid...
From Global to Local Fluctuation Theorems
- Moscow Mathematical Journal
, 2001
"... The Gallavotti-Cohen uctuation theorem suggests a general symmetry in the fluctuations of the entropy production, a basic concept in the theory of irreversible processes, based on results in the theory of strongly chaotic maps. We study this symmetry for some standard models of nonequilibrium steady ..."
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Cited by 4 (3 self)
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The Gallavotti-Cohen uctuation theorem suggests a general symmetry in the fluctuations of the entropy production, a basic concept in the theory of irreversible processes, based on results in the theory of strongly chaotic maps. We study this symmetry for some standard models of nonequilibrium steady states. We give a general strategy to derive a local uctuation theorem exploiting the Gibbsian features of the stationary space-time distribution. This is applied to spin ip processes and to the asymmetric exclusion process.
Nonequilibrium fluctuations in small systems: From physics to biology
- Advances in Chemical Physics
, 2006
"... In this paper I am presenting an overview on several topics related to nonequilibrium fluctuations in small systems. I start with a general discussion about fluctuation theorems and applications to physical examples extracted from physics and biology: a bead in an optical trap and single molecule fo ..."
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Cited by 3 (1 self)
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In this paper I am presenting an overview on several topics related to nonequilibrium fluctuations in small systems. I start with a general discussion about fluctuation theorems and applications to physical examples extracted from physics and biology: a bead in an optical trap and single molecule force experiments. Next I present a general discussion on path thermodynamics and consider distributions of work/heat fluctuations as large deviation functions. Then I address the topic of glassy dynamics from the perspective of nonequilibrium fluctuations due to small cooperatively rearranging regions. Finally, I
On the Definition of Entropy Production, Via Examples
, 1999
"... We present a definition of entropy production rate for classes of deterministic and stochastic dynamics. The point of departure is a Gibbsian representation of the steady state pathspace measure for which `the density' is determined with respect to the time-reversed process. The Gibbs formalism ..."
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Cited by 2 (1 self)
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We present a definition of entropy production rate for classes of deterministic and stochastic dynamics. The point of departure is a Gibbsian representation of the steady state pathspace measure for which `the density' is determined with respect to the time-reversed process. The Gibbs formalism is used as a unifying algorithm capable of incorporating basic properties of entropy production in nonequilibrium systems. Our definition is motivated by recent work on the Gallavotti-Cohen (local) fluctuation theorem and it is illustrated via a number of examples.
Entropy Production for Interacting Particle Systems
"... The present article provides a mathematical intoduction to the concept of entropy production in stochastic dynamics. We discuss the mean rate of entropy production for a class of interacting particle systems. ..."
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Cited by 2 (2 self)
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The present article provides a mathematical intoduction to the concept of entropy production in stochastic dynamics. We discuss the mean rate of entropy production for a class of interacting particle systems.

